Development of a high pressure hydrometallurgical process for the extraction of iron from iron oxide bearing materials (2024)

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Research on High-Pressure Hydrochloric Acid Leaching of Scandium, Aluminum and Other Valuable Components from the Non-Magnetic Tailings Obtained from Red Mud after Iron Removal

Dmitriy Zinoveev

Red mud is a hazardous waste of the alumina industry that contains high amounts of iron, aluminum, titanium and rare-earth elements (REEs). One of the promising methods for the extraction of iron from red mud is carbothermic reduction with the addition of sodium salts. This research focuses on the process of hydrochloric high-pressure acid leaching using 10 to 20% HCl of two samples of non-magnetic tailings obtained by 60 min carbothermic roasting of red mud at 1300 °C and the mixture of 84.6 wt.% of red mud and 15.4 wt.% Na2SO4 at 1150 °C, respectively, with subsequent magnetic separation of metallic iron. The influence of temperature, leaching duration, solid-to-liquid-ratio and acid concentration on the dissolution behavior of Al, Ti, Mg, Ca, Si, Fe, Na, La, Ce, Pr, Nd, Sc, Zr was studied. Based on the investigation of the obtained residues, a mechanism for passing valuable elements into the solution was proposed. It has shown that 90% Al, 91% Sc and above 80% of other REEs can b...

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Experimental study on the beneficiation of low-grade iron ore fines using hydrocyclone desliming, reduction roasting and magnetic separation

2014 •

Steven P Suthers, Venkata Nunna, Sarath Hapugoda

Beneficiation of -2 mm low-grade iron ore tailings (50.7% Fe, 10.8% SiO2 and 4.4% Al2O3) from Western Australia was studied. The sample consisted of hydrohematite, goethite and quartz, with lesser kaolinite and shale. Two processing options were tested, being wet high-intensity magnetic separation (WHIMS) either using deslimed or untreated feed, and reduction (magnetising) roasting of deslimed feed followed by Davis tube tests. WHIMS tests using deslimed feed gave a product having 55.4% Fe, 6.1% SiO2 and 2.7% Al2O3, while the iron recovery was 55.7%. The calcined iron grade was 62.1% Fe. Davis tube tests using deslimed feed that had been reduction roasted at 700°C using a 1:1 mixture of CO/CO2 gave a product with 63.2% Fe, 5.4% SiO2 and 2.9% Al2O3, while the iron recovery was 60.1%. Overall, desliming followed by reduction roasting and Davis tube tests produced the highest grade product with the highest iron recovery.

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Development of a high pressure hydrometallurgical process for the extraction of iron from iron oxide bearing materials (2024)

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